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Which of the following gases would you expect to have the largest van der Waals a constant value?


A) Kr
B) N2
C) O2
D) H2
E) Ne

F) B) and D)
G) A) and E)

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Which is the dominant interaction between water molecules?


A) ion-ion
B) ion-dipole
C) dipole-dipole
D) hydrogen bonding
E) dispersion or London forces

F) B) and E)
G) A) and D)

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Which of the following requires the smallest energy to separate the ions?


A) CaF2
B) KF
C) NaF
D) MgF2
E) LiCl

F) B) and C)
G) A) and C)

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Identify the dominant intermolecular interaction(s) that must be overcome when solid CO2 sublimes and H2O melts.

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Carbon dioxide is nonpolar, so...

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Which alkane compound has the highest boiling point?


A) C4H10
B) C5H12
C) C6H14
D) C7H16
E) C8H18

F) C) and E)
G) A) and B)

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Which of the following statements does not correctly characterize the rate of evaporation of a liquid? I. Increases with increasing temperature because molecules have higher kinetic energies. II. Increases with increasing surface area of the liquid because more molecules are located at the surface. III. Increases with stronger intermolecular forces because molecules in the liquid repel each other more.


A) I only
B) II only
C) III only
D) I and II only
E) II and III only

F) A) and C)
G) D) and E)

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Which of the following statements correctly characterizes the rate of evaporation of a liquid? I. Increases with increasing temperature because molecules have higher kinetic energies. II. Increases with increasing surface area of the liquid because more molecules are located at the surface. III. Decreases with stronger intermolecular forces because molecules are less able to escape from the surface of the liquid.


A) I only
B) II only
C) III only
D) I and II only
E) All three: I, II, and III

F) B) and E)
G) C) and D)

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Which is the dominant interaction between oxygen and nitrogen molecules in air?


A) ion-ion
B) ion-dipole
C) dipole-dipole
D) hydrogen bonding
E) dispersion or London forces

F) A) and E)
G) B) and E)

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When sodium chloride dissolves in water, how do the water molecules orient around the ions?


A) Water molecules are randomly oriented around the ions.
B) The hydrogen atoms point toward both the sodium and the chloride.
C) The oxygen atoms point toward both the sodium and the chloride.
D) Around sodium the hydrogen atoms point toward the sodium, and around chloride the oxygen atoms point toward the chloride.
E) Around sodium the oxygen atoms point toward the sodium, and around chloride the hydrogen atoms point toward the chloride.

F) All of the above
G) C) and D)

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When two liquids mix completely in all proportions, they are ________


A) soluble.
B) miscible.
C) insoluble.
D) solvated.
E) ubiquitous.

F) None of the above
G) A) and E)

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Which liquid, water or ethanol, would you expect to have the higher surface tension and viscosity? Explain.

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Water would have higher surface tension ...

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Define the term vapor pressure.

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Vapor pressure is the pressure...

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Of the two compounds shown below, one is slightly soluble in water and the other is insoluble in water. Identify the slightly soluble compound and explain why it is soluble in water. I. ClCH2CH2Cl Of the two compounds shown below, one is slightly soluble in water and the other is insoluble in water. Identify the slightly soluble compound and explain why it is soluble in water. I. ClCH<sub>2</sub>CH<sub>2</sub>Cl   II. CHCl<sub>2</sub>CH<sub>3 </sub>   A)  I because it can form hydrogen bonds with water at each end of the molecule. B)  I because it has stronger dispersion interactions with water. C)  II because it has stronger dipole-dipole interactions with water. D)  II because it has stronger dispersion interactions with water. E)  I because it is nonpolar. II. CHCl2CH3 Of the two compounds shown below, one is slightly soluble in water and the other is insoluble in water. Identify the slightly soluble compound and explain why it is soluble in water. I. ClCH<sub>2</sub>CH<sub>2</sub>Cl   II. CHCl<sub>2</sub>CH<sub>3 </sub>   A)  I because it can form hydrogen bonds with water at each end of the molecule. B)  I because it has stronger dispersion interactions with water. C)  II because it has stronger dipole-dipole interactions with water. D)  II because it has stronger dispersion interactions with water. E)  I because it is nonpolar.


A) I because it can form hydrogen bonds with water at each end of the molecule.
B) I because it has stronger dispersion interactions with water.
C) II because it has stronger dipole-dipole interactions with water.
D) II because it has stronger dispersion interactions with water.
E) I because it is nonpolar.

F) A) and B)
G) D) and E)

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Which statement about a hydrogen bond is not correct?


A) Hydrogen bonds involve hydrogen bonded to carbon, nitrogen, oxygen, or fluorine.
B) In a hydrogen bond, the hydrogen atom on one molecule is attracted to unpaired electrons associated with nitrogen, oxygen, or fluorine on another molecule.
C) A hydrogen bond can be thought of as a very strong dipole-dipole interaction.
D) The presence of hydrogen bonds leads to anomalously high boiling points for liquids.
E) Hydrogen bonds stabilize the double helix structure of DNA.

F) A) and D)
G) A) and C)

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Molecular nitrogen (N2) interacts with water and is sparingly soluble in water due to ________


A) dispersion forces.
B) dipole-induced dipole forces.
C) ion-dipole forces.
D) hydrogen bonding.
E) dipole-dipole forces.

F) B) and E)
G) A) and E)

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Which statement about vapor pressure of a pure liquid is not correct?


A) The vapor pressure is the pressure of the gas at a given temperature in equilibrium with its liquid phase.
B) The temperature at which the vapor pressure equals 760 torr is called the normal boiling point of the substance.
C) The vapor pressure increases with increasing temperature.
D) The vapor pressure increases with increasing surface area of the liquid.
E) Substances with weak intermolecular forces have high vapor pressures at a given temperature.

F) B) and D)
G) A) and E)

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Sketch a phase diagram for water and correctly label all the parts (areas, lines, points, key temperatures).

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Boiling points can also be cal...

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The phase diagram for carbon dioxide is shown below. What is the phase that exists at room temperature (22oC) and 100 atm pressure? The phase diagram for carbon dioxide is shown below. What is the phase that exists at room temperature (22<sup>o</sup>C)  and 100 atm pressure?   A)  gas B)  liquid C)  solid I D)  supercritical fluid E)  solid II


A) gas
B) liquid
C) solid I
D) supercritical fluid
E) solid II

F) C) and D)
G) None of the above

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Which of the following compounds will have the strongest dipole-dipole interactions between its molecules?


A) CF4
B) CH4
C) CH3F
D) CH2F2
E) CH3Cl

F) B) and C)
G) All of the above

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Which of the following compounds would you most appropriately call hydrophobic?


A) CH4
B) H2CO
C) CO
D) HCl
E) NaCl

F) All of the above
G) None of the above

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